Stochastic approach to Fisher and Kolmogorov, Petrovskii, and Piskunov wave fronts for species with different diffusivities in dilute and concentrated solutions

Gabriel Morgado, Bogdan Nowakowski, and Annie Lemarchand

Physica A, Volume 558, 15 November 2020, 124954

Abstract

A wave front of Fisher and Kolmogorov, Petrovskii, and Piskunov type involving two species A and B with different diffusion coefficients DA and DB is studied using a master equation approach in dilute and concentrated solutions. Species A and B are supposed to be engaged in the autocatalytic reaction A+B → 2A. Contrary to the results of a deterministic description, the front speed deduced from the master equation in the dilute case sensitively depends on the diffusion coefficient of species B. A linear analysis of the deterministic equations with a cutoff in the reactive term cannot explain the decrease of the front speed observed for DB > DA. In the case of a concentrated solution, the transition rates associated with cross-diffusion are derived from the corresponding diffusion fluxes. The properties of the wave front obtained in the dilute case remain valid but are mitigated by cross-diffusion which reduces the impact of different diffusion coefficients.

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This project has received funding from the European Union’s Horizon 2020 research and innovation programme under the Marie Skłodowska-Curie grant agreement No. 711859.